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The monophosphaamidine functional group

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dc.contributor.advisor Boeré, René T. Masuda, Jason Douglas University of Lethbridge. Faculty of Arts and Science 2007-05-12T19:23:58Z 2007-05-12T19:23:58Z 2002
dc.description xxxii, 280 leaves : ill. ; 28 cm. en
dc.description.abstract The synthesis and characterization of two new bulky N,P-monophosphaamidines (also known as C-aminophosphaalkenes) are described. These phosphorus analogues to amidines are shown to exhibit isomerism and tautomerism in solution that is characteristic tothe amidine functional group. In addition, the nature of the P=C-N system is examined using DFT techniques. Metal complexes of the title compounds with Group 6 metal carbonyls (L-M(CO)5, M=Cr,Mo,W) are also described. A new primary phosphane is reported that contains the sterically bulky, 2,6-diisoropylphenyl (Dip) group, along with mono and disilylated derivatives. Also included is the synthesis and characterization of a new bulky N,N',P-monophosphaguanidine. en
dc.language.iso en_US en
dc.publisher Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2002 en
dc.relation.ispartofseries Thesis (University of Lethbridge. Faculty of Arts and Science) en
dc.subject Phosphorus compounds en
dc.subject Amidines en
dc.subject Dissertations, Academic en
dc.title The monophosphaamidine functional group en
dc.type Thesis en
dc.publisher.faculty Arts and Science
dc.publisher.department Department of Chemistry and Biochemistry Masters

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